It looks a bit as if the HV secondary is split between the two legs of the core. Assuming that is the case and the two sections are equal, opening the centre tap should give two 3300 volt secondaries, with the outer ends in antiphase. You can check this by feeding the primary from a low voltage transformer -say 4 volts - when you should get about 55 volts from each side.
With 3300 - 0 - 3300, you would get around 4.5kV with capacitor input and around 2600 or so with choke input.
You will need a dedicated 30 Amp cooker type spur for the mains, too. What is the mains like where you live - many country areas will see appreciable sag when that sort of load comes on, and most UK properties are good only for feeds of 60 Amps - maybe 100 in newer ones. I presume you are well away from neighbours, because if not, EMC will almost certainly be a problem - and in your own property, too. You need a good separation from your antennas, for it is not unknown for the RCD (GFCI in US) to get upset with RF. Consider, too, the ratings of antennas and tuners in terms of voltage.
Additionally, although Ofcom turn a bit of a blind eye to exceeding the power limit, if they find you running 5 times the licenced power, they may well get a bit uppity!